Abstract
In the title complex, [Zn(1,4-BDOA)(H2O)4]n or [Zn(C10H8O6)(H2O)4]n (where 1,4-BDOA2− is the benzene-1,4-dioxyacetate dianion), the ZnII atom and the 1,4-BDOA2− ligand build up a one-dimensional polymer chain along c. The ZnII atom, located on an inversion center, shows an octahedral coordination geometry, defined by two carboxyl O atoms of different benzene-1,4-dioxyacetate ligands and four water molecules. Adjacent ZnII atoms are bridged by bis-monodentate carboxylate groups of the centrosymmetric 1,4-BDOA2− ligands, to furnish the one-dimensional chain along the c axis; the Zn⋯Zn separation within the polymer is 14.717 (3) A. A hydrogen-bonded supramolecular architecture is formed via O—H⋯O intermolecular hydrogen bonds.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
