Abstract
In the title compound, {[Cu(C10H8N2)(H2O)4](C4F4O4)·4H2O}n, the CuII atom adopts an elongated octahedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond. The 4,4′-bipyridyl ligand links the CuII atoms into a linear chain along the b axis. O—H⋯O hydrogen-bonding interactions between the cationic chains and the tetrafluoridosuccinate anions and the free water molecules generate a three-dimensional supramolecular network.
Highlights
In the title compound, {[Cu(C10H8N2)(H2O)4](C4F4O4)4H2O}n, the CuII atom adopts an elongated octahedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond
Symmetry codes: (v) −x+1/2, −y+3/2, −z+1; (vi) −x+1/2, y+1/2, −z+1/2; (vii) −x+1/2, y+1/2, −z+3/2
Summary
ISSN 1600-5368 catena-Poly[[[tetraaquacopper(II)]-l4,40 -bipyridyl-j2N:N0 ] tetrafluoridosuccinate tetrahydrate]. Faculty of Materials Science & Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, People’s Republic of China. R factor = 0.027; wR factor = 0.085; data-to-parameter ratio = 16.6. In the title compound, {[Cu(C10H8N2)(H2O)4](C4F4O4)4H2O}n, the CuII atom adopts an elongated octahedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond. The 4,40 bipyridyl ligand links the CuII atoms into a linear chain along the b axis. O—H O hydrogen-bonding interactions between the cationic chains and the tetrafluoridosuccinate anions and the free water molecules generate a three-dimensional supramolecular network
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
