Abstract

In the crystal structure of the title compound, [Co(C7H7N2O4)(H2O)4]Cl(OH)·2H2O, the cations form a polycationic chain that propagates along the b axis of the monoclinic unit cell. The CoIII atom and two coordinated water mol­ecules lie on special positions of site symmetry m. The C7H7N2O4 anion displays crystallographic mirror symmetry. The chloride and hydroxide anions are disordered and they inter­act, along with the uncoordinated water mol­ecule, with the polycationic chain to form a three-dimensional, hydrogen-bonded network.

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