Abstract
The title complex, {[Sr(C7H5O6S)2(H2O)4]·2H2O}n, exists as a ladder chain of SrII ions connected by 3-carboxy-4-hydroxybenzenesulfonate anions through μ2-sulfonate and carboxyl groups, and solvent water molecules, forming a three-dimensional hydrogen-bonded framework. The SrII ion exhibits a distorted square antiprismatic coordination geometry defined by three O atoms of two sulfonate groups, one carboxyl O and four water molecules. The 3-carboxy-4-hydroxybenzenesulfonate anions show two types of coordination to strontium, viz. μ2-sulfonate + monodentate-carboxyl bridging and monodentate sulfonate–O coordination.
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