Abstract

The asymmetric unit of the title compound, [Ag(C9H7N2)]n, contains two independent AgI ions and two 2-phenyl­imidazolate (L) ligands. Each AgI centre is linearly coordinated by two N atoms [Ag—N 2.092 (3)–2.097 (3) Å]. Ligands L bridge AgI ions into polymeric chains parallel to the c axis, with Ag⋯Ag separations of 6.232 (2) and 6.254 (2) Å. No inter­actions between the Ag centres from neighbouring chains are observed.

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