Abstract

In the title compound, [Cu(C13H9NO3)(C5H5N)], the CuII atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu—O bond [2.3520 (16) Å] is much longer than the basal Cu—O and Cu—N bonds [1.9139 (14)–2.0136 (17) Å]. The carboxyl­ate group bridges CuII atoms, forming a zigzag chain along the a axis.

Highlights

  • Bruker APEXII CCD diffractometerR factor = 0.026; wR factor = 0.069; data-to-parameter ratio = 12.7

  • In the title compound, [Cu(C13H9NO3)(C5H5N)], the CuII atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position

  • We report here the crystal structure of the title CuII complex, (I)

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Summary

Bruker APEXII CCD diffractometer

R factor = 0.026; wR factor = 0.069; data-to-parameter ratio = 12.7. In the title compound, [Cu(C13H9NO3)(C5H5N)], the CuII atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu—O bond [2.3520 (16) Å] is much longer than the basal Cu—O and. The carboxylate group bridges CuII atoms, forming a zigzag chain along the a axis

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