Abstract
In the title compound, [Cu(C7H3NO4)(C5H5N)]n, the CuII atom is in a slightly distorted octahedral coordination environment. Each CuII atom is bound to two N atoms and one O atom of the pyridinedicarboxylate (PDA) ligand in a tridentate manner, one N atom of the pyridine molecule and two bridging carboxylate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C—H⋯O and π–π interactions into a three-dimensional supramolecular network structure. The centroid–centroid distance between the π–π interacting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu.
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