Catena-Poly[{di-μ-azido-bis[azido(N,N-diethylethane-1,2-diamine)copper(II)]} [[azido(N,N-diethylethane-1,2-diamine)copper(II)]-μ-azido

Abstract

The title complex, {[Cu2(N3)4(C6H16N2)2][Cu(N3)2(C6H16N2)]}n, consists of an end-on azide-bridged dinuclear copper(II) complex and an end-to-end azide-bridged polynuclear copper(II) complex. Each Cu atom is five-coordinated by two N atoms of N,N-diethyl­ethane-1,2-diamine and by three N atoms from three azide ligands, forming a slightly distorted square-pyramidal coordination environment.