Abstract

In the title polymeric compound, [Mn(C7H4O5S)(C12H8N2)(H2O)2]·0.32H2O, which was synthesized by a combination of hydro­thermal reaction and solution evaporation, each MnII ion approximates an octa­hedral geometry and each 3-sulfonatobenzoate ligand links two metal atoms in a μ2 mode. Extensive hydrogen bonds between water mol­ecules and sulfonate groups give rise to a three-dimensional network in the crystal structure.

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