Abstract
The title compound, [CuCl(C9H9N5)]n, prepared by solvothermal synthesis, is a new homometallic CuI–olefin coordination polymer in which the CuI atoms are linked by the 3-(2-allyl-2H-tetrazol-5-yl)pyridine ligands and are each bonded to one terminal Cl atom. The organic ligand acts as a bidentate ligand bridging two neighboring Cu centers through the bonds to the N atom of the pyridine ring and the double bond of the allyl group. Weak Cu⋯Cl [3.136 (8) Å), C—H⋯Cl and C—H⋯N interactions connect the coordination polymers into a three-dimensional structure.
Highlights
The title compound, [CuCl(C9H9N5)]n, prepared by solvothermal synthesis, is a new homometallic CuI–olefin coordination polymer in which the CuI atoms are linked by the 3-(2allyl-2H-tetrazol-5-yl)pyridine ligands and are each bonded to one terminal Cl atom
Symmetry codes: (iii) x+1, y, z; (iv) −x, −y+1, −z
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.005 A; R factor = 0.045; wR factor = 0.104; data-to-parameter ratio = 15.9. The title compound, [CuCl(C9H9N5)]n, prepared by solvothermal synthesis, is a new homometallic CuI–olefin coordination polymer in which the CuI atoms are linked by the 3-(2allyl-2H-tetrazol-5-yl)pyridine ligands and are each bonded to one terminal Cl atom. The organic ligand acts as a bidentate ligand bridging two neighboring Cu centers through the bonds to the N atom of the pyridine ring and the double bond of the allyl group. Weak CuÁ Á ÁCl [3.136 (8) A ), C—HÁ Á ÁCl and C— HÁ Á ÁN interactions connect the coordination polymers into a three-dimensional structure. Crystal data [CuCl(C9H9N5)] Mr = 286.21 Triclinic, P1 a = 7.3005 (15) Ab = 7.6560 (15) Ac = 9.981 (2) A = 80.51 (3) = 77.00 (3)
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