Abstract
The title compound, [Cu(bix)Br]n·nH2O [bix = 1,4-bis(imidazol-l-ylmethyl)benzene] or {[CuBr(C14H14N4)]·H2O}n, was synthesized by the hydrothermal method. The CuI centre has an unusual 2+1 trigonal coordination geometry. There is a crystallographic centre of inversion at the middle of each benzene ring. Each bix ligand binds with two CuI atoms to form a linear chain. These chains stack, forming microchannels along the a-axis direction which are occupied by solvent water molecules.
Published Version
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