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Abstract
In the crystal structure of the title compound, {[Mn(NCSe)2(C12H10N2)(CH3OH)2]·C12H10N2}n, the MnII cation is coordinated by two terminal N-bonded selenocyanate anions, two methanol molecules and two 1,2-bis(pyridin-4-yl)ethene (bpe) ligands within a slightly distorted octahedral geometry. The MnII cations are linked into chains along the c-axis direction by the bpe ligands, which are further connected by intermolecular O—H⋯N hydrogen bonding between the methanol H atoms and additional bpe molecules that are not coordinated to the metal atoms. The MnII cation and both crystallographically independent bpe ligands are located on centers of inversion, whereas the selenocyanate and methanol ligands occupy general positions.
Highlights
In the crystal structure of the title compound, {[Mn(NCSe)2(C12H10N2)(CH3OH)2]C12H10N2}n, the MnII cation is coordinated by two terminal N-bonded selenocyanate anions, two methanol molecules and two 1,2-bis(pyridin-4-yl)ethene ligands within a slightly distorted octahedral geometry
MnII cations are linked into chains along the c-axis direction by the bpe ligands, which are further connected by intermolecular O—H N hydrogen bonding between the methanol H atoms and additional bpe molecules that are not coordinated to the metal atoms
The MnII cation and both crystallographically independent bpe ligands are located on centers of inversion, whereas the selenocyanate and methanol ligands occupy general positions
Summary
ISSN 1600-5368 catena-Poly[[[bis(methanol-jO)bis(selenocyanato-jN)manganese(II)]-l1,2-bis(pyridin-4-yl)ethene-j2N:N0 ] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-EythStrasse 2, 24118 Kiel, Germany R factor = 0.041; wR factor = 0.112; data-to-parameter ratio = 14.7.
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