Catena-Poly[[(benzyl-diphenyl-phosphine-κP)silver(I)]-μ-nitrato-κ2 O:O'-[(benzyl-diphenyl-phosphine-κP)silver(I)]-μ-nitrato-κ4 O,O':O',O''

Abstract

The structure of the title complex, [Ag2(NO3)2(C19H17P)2] n , reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetra-hedral shape.