Abstract
In the title compound, [Cu(C4H5O4)(H2O)]n, the iminodiacetate (ida) ligands link the CuII atoms into polymeric zigzag chains running along [010]. Each CuII ion is five-coordinated in a distorted square-pyramidal geometry by one N and two O atoms from an ida ligand, one O atom from the neighbouring ida ligand and one water O atom. In the crystal, the polymeric chains are held together via intermolecular O—H⋯O and N—H⋯O hydrogen bonds.
Highlights
H atoms treated by a mixture of independent and constrained refinement max = 0.45 e Å3
Each CuII ion is fivecoordinated in a distorted square-pyramidal geometry by one
Symmetry codes: (iii) x, −y+1/2, z+1/2; (iv) x+1, −y+1/2, z+1/2
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.45 e Å3. R factor = 0.034; wR factor = 0.082; data-to-parameter ratio = 14.3. In the title compound, [Cu(C4H5O4)(H2O)]n, the iminodiacetate (ida) ligands link the CuII atoms into polymeric zigzag chains running along [010]. Each CuII ion is fivecoordinated in a distorted square-pyramidal geometry by one. N and two O atoms from an ida ligand, one O atom from the neighbouring ida ligand and one water O atom. The polymeric chains are held together via intermolecular O—.
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