Abstract
In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]·2H2O}n, an infinite [1-10] chain is formed by the linking of [Zn(C10H8N2)(H2O)]2+ entities by bridging, monodentate furan-2,5-dicarboxylate dianionic linkers. The Zn2+ coordination geometry is a trigonal bipyramid, with one N atom (from 2,2′-bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each ZnII atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is 87.19 (8)°. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water molecules generate a layer motif parallel to (001).
Highlights
N atom and one O atom in the axial positions
H atoms treated by a mixture of independent and constrained refinement max = 0.67 e Å3
In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]2H2O}n, an infinite [110] chain is formed by the linking of [Zn(C10H8N2)(H2O)]2+ entities by bridging, monodentate furan-2,5-dicarboxylate dianionic linkers
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.67 e Å3. R factor = 0.036; wR factor = 0.102; data-to-parameter ratio = 15.0. Symmetry code: (i) x þ 1; y 1; z. In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]2H2O}n, an infinite [110] chain is formed by the linking of [Zn(C10H8N2)(H2O)]2+ entities by bridging, monodentate furan-2,5-dicarboxylate dianionic linkers. The. N atom (from 2,20 -bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each ZnII atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is. O—H O hydrogen bonds involving both the coordinated and uncoordinated water molecules generate a layer motif parallel to (001)
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
