Abstract
In the title complex, {[Zn(C4O4)(C12H8N2)(H2O)]·H2O}n, the pentacoordinated ZnII ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetylenedicarboxylate anions and a water O atom in a distorted trigonal–bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [2-10] and is stabilized by O—H⋯O hydrogen bonds.
Highlights
1,10-phenanthroline ligand, two O atoms from two bridging acetylenedicarboxylate anions and a water O atom in a distorted trigonal–bipyramidal geometry
H atoms treated by a mixture of independent and constrained refinement max = 0.71 e Å3
The crystal structure is characterized by polymeric zigzag chains running parallel to
Summary
Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia H atoms treated by a mixture of independent and constrained refinement max = 0.71 e Å3 R factor = 0.041; wR factor = 0.111; data-to-parameter ratio = 14.0. Hydrogen-bond geometry (Å, ). In the title complex, {[Zn(C4O4)(C12H8N2)(H2O)]H2O}n, the pentacoordinated ZnII ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetylenedicarboxylate anions and a water O atom in a distorted trigonal–bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [210] and is stabilized by O—H O hydrogen bonds.
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