Abstract
In the crystal structure of the yellow copper(I) compound, {[Cu2(SO4)(C10H8N2)2]·4H2O}n, one [(C10H8N2)2Cu]n chain is stacked over another [Cu⋯Cu = 3.180 (1) A]; the two chains are bridged by SO4 groups through two Cu—O bonds into a double-chain motif. The SO4 groups are located alternately on opposite sides of the double chain and lie on twofold rotation axes. The disordered solvent water molecules occupy the space between the double chains. The CuI atom exists in a T-shaped environment.
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