Abstract
The title complex, catena-poly[dibromocadmium-μ-3-dimethylamino-1-propanethiolato], contains polymeric chains of alternating Cd and S atoms with Cd-S bond lenght of 2.515(3) and 2.520(3) A. Distorted tetrahedral coordination of Cd [with a wide S-Cd-S angle of 126.95(5) o ] is completed by two Br ligands [Cd-Br 2.5834(15) and 2.6400(14) A]. The longer Cd-Br bond is to a Br atom involved in inter-chain hydrogen bonding with the ammonium group of a mercaptoamine ligand of an adjacent chain, to give two-dimensional sheets
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