Catalytic wet air oxidation of dye pollutants by polyoxomolybdate nanotubes under room condition

Abstract

In order to develop a catalyst with high activity and stability for catalytic wet air oxidation of pollutant dyes at room condition, a new polyoxometalate Zn1.5PMo12O40 with nanotube structure was prepared using biological template. The structure and morphology were characterized using infrared (IR) spectra, UV–vis diffuse reflectance spectra (DR-UV–vis), elemental analyses, X-ray powder diffraction (XRD), and transmission electron microscopy (TEM). And the degradation of Safranin-T (ST), a hazardous textile dye, under air at room temperature and atmospheric pressure was studied as a model experiment to evaluate the catalytic activity of this polyoxomolybdate catalyst. The results show that the catalyst has an excellent catalytic activity in treatment of wastewater containing 10mg/L ST, and 98% of color and 95% of chemical oxygen demand (COD) can be removed within 40min. And the organic pollutant of ST was totally mineralized to simple inorganic species such as HCO3−, Cl− and NO3− during this time (total organic carbon (TOC) decreased 92%). The structure and morphology of the catalyst under different cycling runs show that the catalyst are stable under such operating conditions and the leaching tests show negligible leaching effect owning to the lesser dissolution. So this polyoxomolybdate nanotube is proved to be a heterogeneous catalyst in catalytic wet air oxidation of organic dye.