Abstract
Three half-sandwich titanium complexes with a pendant ethereal group, CH3OCH2CH2CpTiCl3, CH3OCH(CH3)CH2CpTiCl3, and tetrahydrofurfurylcyclopentadienyltitanium trichloride activated by MAO have been found to trimerize ethylene with high selectivity and moderate activity. Compared with the catalytic behavior of CpTiCl3/MAO and n-Pr-CpTiCl3/MAO, we can identify that the pendant ethereal group plays an important role in this selective trimerization process. Their different catalytic behavior toward temperature is discussed.
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