Abstract
The influence of the electrochemical double layer (EDL) structure on the electrochemical processes in ionic liquids is an intriguing subject. The complex layered structure of the EDL and its restructuring have been shown to strongly affect metal deposit morphology and electrochemical reaction kinetics. In this work, we demonstrate that the breakdown of an ionic liquid containing TFSI anions can be catalyzed through the addition of Li+ cations. We ascribe this catalytic effect to the change in the EDL structure: the Li+ cations preferentially adsorb on the electrode surface and drag the TFSI anions with them, facilitating their reduction. The decomposition of the ionic liquid leads to the formation of an SEI layer, which is studied using an electrochemical quartz crystal microbalance.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
