Abstract

Catalytic chemistry of zeolites has been studied in the oxidative dehydrogenation reaction of various organic compounds. Molecular sieve properties of zeolites were found to have a pronounced effect on the direction of oxidative hydrocarbon conversion and catalyst activity and selectivity. Interaction of various zeolites with molecular oxygen and compounds being oxidized has been investigated by e.p.r, and thermodesorption techniques. Kinetics of the reaction have been studied to elucidate the reaction mechanism. It is possible to change the direction of hydrocarbon conversion and obtain desirable end products by varying zeolite structure and composition which indicates a promising role of zeolites in oxidative catalysis.

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