Abstract
Trinuclear thio complexes of rhenium based on Re3S7 and Re3S4 cluster groupings have been synthesized and studied as catalysts in liquid-phase hydrogenation of m-nitrobenzoic acid. Thio complexes containing as Re3S7 cluster surrounded by hydroxo groups are the most active. Complexes with an Re3S4 cluster are less active. Reversible Re3S7 ⇆ Re3S4 + S8 transitions were found to be possible in solution.
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