Abstract

1. Characteristic features of the catalytic action of the PdCl2·CuCl2/zeolite systems obtained by the impregnation method were studied during the oxidation of C2-C4 olefins to carbonyl compounds. In activity, selectivity, and stability, systems based on synthetic faujasites are superior to both the PdCl2 · CuCl2/ Al2O3 (SiO2; amorphous aluminosilicate) and the ion-exchange-produced PdCu zeolites already studied. 2. Conditions were found ensuring a 98–99% selectivity of the conversion of C2H4 to acetaldehyde, and C3H6 to acetone.

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