Abstract

Gold supported on cobalt oxide has been successfully synthesized through a colloidal precipitation method and tested in toluene and p-xylene total oxidation. It has been demonstrated that the catalytic activity of Au/Co 3O 4 for toluene and p-xylene oxidation is much higher than that of Au/Al 2O 3 and Au/MgO in spite of its lower BET surface area and larger gold crystalline size. The enhanced catalytic activity in toluene and p-xylene oxidation has been linked to a high concentration of superficial electrophilic oxygen species and oxygen vacancies, which may be originated from a strong interaction in the colloidal Au–Co 3O 4 system.

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