Abstract
AbstractThe Deacon reaction (HCI + 1/4 O2 ⇋ 1/2 Cl2 + 1/2 H2O) was studied in a catalytic fluid bed reactor. Reaction rates found from measurements in differential and integral reactors were represented by the Langmuir‐Hinshelwood type rate equation. Considering the effect of catalysts in the dilute phase, it was found that conversions in a fluid bed reactor can be calculated without any modifying parameters. It is pointed out that the wake fraction, which has been necessary to consider for fast reactions in a fluid bed reactor, is attributed to the dilute phase effect.
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