Abstract
This paper investigated the enhancement of plasma on dimethyl sulfide (DMS) removal over commercial V-W/Ti catalysts. The effects of catalyst composition, discharge power, and gas temperature on DMS removal in the plasma-based system were analyzed. The results showed that the V0.9–W/Ti catalyst exhibited the best performance toward DMS removal due to its highest reducibility among the employed samples. The introduction of plasma exhibited a synergistic effect on catalysts and significantly enhanced the removal of DMS over the studied temperature range, especially in high discharge power cases. The activation energy $E_{a}$ of DMS removal in the presence of plasma was dramatically reduced to less than 10% of the catalysis only case, indicating different DMS removal pathways in plasma-activated catalysis system. The reaction mechanisms of DMS were also discussed based on the reaction products.
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