Abstract

A reaction rate method is described for the microdetermination of iron. The method is based on the catalytic action of iron on the reaction of 2,4-diaminophenol with hydrogen peroxide. The effect of reagent concentration is studied and the maximum tolerable amounts of interfering ions are determined. Procedures for the determination of 2.8 × 10 −3 to 2.8 × 10 −2 μg/ml are given. Quantities of 2.8 × 10 −3 to 2.8 × 10 −2 μg/ml could be determinated with a relative error of about 2%.

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