Catalytic Mechanism of Oxygen Vacancies in Perovskite Oxides for Lithium-Sulfur Batteries.

Abstract

Defective materials have been demonstrated to possess adsorptive and catalytic properties in lithium-sulfur (Li-S) batteries, which can effectively solve the problems of lithium polysulfides (LiPSs) shuttle and sluggish conversion kinetics during charging and discharging of Li-S batteries. However, there is still a lack of research on the quantitative relationship between the defect concentration and the adsorptive-catalytic performance of the electrode. In this work, perovskites Sr0.9 Ti1- x Mnx O3- δ (STMnx ) (x=0.1-0.3) with different oxygen-vacancy concentrations are quantitatively regulated as research models. Through a series of tests of the adsorptive property and electrochemical performance, a quantitative relationship between oxygen-vacancy concentration and adsorptive-catalytic properties is established. Furthermore, the catalytic mechanism of oxygen vacancies in Li-S batteries is investigated using density functional theory calculations and insitu experiments. The increased oxygen vacancies can effectively increase the binding energy between perovskite and LiPSs, reduce the energy barrier of LiPSs decomposition reaction, and promote LiPSs conversion reaction kinetics. Therefore, the perovskite STMn0.3 with high oxygen-vacancy concentrations exhibits excellent LiPSs adsorptive and catalytic properties, realizing high-efficiency Li-S batteries. This work is helpful to realize the application of the quantitative regulation strategy of defect engineering in Li-S batteries.