Abstract
Recent results on hyd rode halogenation (HDH) of alkyl halides, freons, aryl halides, polychlorinated derivatives of benzodioxines and biphenyls, and other compounds in the presence of heterogeneous and homogeneous catalysts are generalized, Effective and selective hydrodehalogenation proceedsvia anion or radical anion intermediates. Special attention is given to the nature of the source of the hydrogen replacing the halogen.
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