Abstract
The gas phase dichloromethane hydrodechlorination was studied in the absence and in the presence of traces of chloroform and tetrachloroethylene over 0.3–0.7 wt.% Pd supported on commercial alumina or sol–gel titania. Turnover frequencies (TOFs), rate constants, reaction orders and activation energies were determined. Catalysts with the higher palladium loadings on both supports were much more active. A decreased activity was observed when traces of chloroform or tetrachloroethylene were added to the feed stream. However, the deactivation effect was lower over alumina-supported catalysts. Selected catalysts were characterized by chemical analysis, BET, chemisorption, TGA and TPR.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
