Catalytic effect of lucunary heteropolyanion containing molybdenum and tungsten atoms on decolorization of direct blue 71

Abstract

Abstract In this research, a lucunary Keggin structure, [PMo 2 W 9 O 39 ] 7− was selected as an efficient homogenous catalyst for degradation of an azo dye (direct blue 71) and a simple method was developed for degradation of DB71. The method is based on the oxidation of azo dye in the presence of a lucunary Keggin form of polyoxometalates, K 7 [PMo 2 W 9 O 39 ]·19H 2 O, as a homogenous catalyst at room temperature. The reaction is monitored spectrophotometrically by measuring the absorbance of dye at λ = 585 nm. Some parameters including concentration of catalyst, concentration of H 2 O 2 , pH and reaction time were investigated and optimized. Results show that K 7 [PMo 2 W 9 O 39 ]·19H 2 O is more efficient in the presence of hydrogen peroxide. Degradation of dye in the presence of the catalyst and H 2 O 2 could lead to the disappearance approximately 65% of dye after 60 min. But degradation for the same experiment performed in the absence of catalyst or in the absence of H 2 O 2 was 22% or 5% respectively. Approximately 87% azo dyes has been eliminated after 90 min in the presence of catalyst, H 2 O 2 and optimize conditions (0.6 g/L of K 7 [PMo 2 W 9 O 39 ]·19H 2 O, 0.08 mol/L hydrogen peroxide and room temperature).