Catalytic Effect of Facile Synthesized TiH1.971 Nanoparticles on the Hydrogen Storage Properties of MgH2.

Zhang Zhang,Yan Yan,Ji Ji,Sun Sun,Zhu Zhu,Lu Lu

doi:10.3390/nano9101370

Abstract

Catalytic doping plays an important role in enhancing the hydrogen storage performance of MgH2, while finding an efficient and reversible catalyst remains to be a great challenge in enhancing the de/rehydrogenation properties of MgH2. Herein, a bidirectional nano-TiH1.971 catalyst was prepared by a wet chemical ball milling method and its effect on hydrogen storage properties of MgH2 was studied. The results showed that all the TiH1.971 nanoparticles were effective in improving the de/rehydrogenation kinetics of MgH2. The MgH2 composites doped with TiH1.971 could desorb 6.5 wt % H2 in 8 min at 300 °C, while the pure MgH2 only released 0.3 wt % H2 in 8 min and 1.5 wt % H2 even in 50 min. It was found that the smaller the size of the TiH1.971 particles, the better was the catalytic effect in promoting the performance of MgH2. Besides, the catalyst concentration also played an important role and the 5 wt %-c-TiH1.971 modified system was found to have the best hydrogen storage performance. Interestingly, a significant hydrogen absorption amount of 4.60 wt % H2 was evidenced for the 5 wt %-c-TiH1.971 doped MgH2 within 10 min at 125 °C, while MgH2 absorbed only 4.11 wt% hydrogen within the same time at 250 °C. The XRD results demonstrated that the TiH1.971 remained stable in cycling and could serve as an active site for hydrogen transportation, which contributed to the significant improvement of the hydrogen storage properties of MgH2.

Highlights

The increase of pollutants such as nitrogen dioxide in the atmosphere, resulted from high consumption of fossil fuels, causes an urgent demand for clean and sustainable energy resources [1]
TiH1.971 with different particle sizes are prepared via a wet chemical ball milling method and the as-milled TiH1.971 nanoparticles are added to MgH2 to improve its hydrogen storage performance
The samples were labeled as MgH2 + 5 wt %-x-TiH1.971, where x stood for the milling time (x = 30 h, 45 h, and 60 h, which were marked as a, b, and c in the following, respectively)

Summary

Introduction

The increase of pollutants such as nitrogen dioxide in the atmosphere, resulted from high consumption of fossil fuels, causes an urgent demand for clean and sustainable energy resources [1]. Liang et al [33] reported improved hydrogen storage performance of MgH2 with 5 wt % transition metals (Ti, V, Mn, Fe, and Ni), in which 5 wt % hydrogen was released from V-modified composite within 200 s at 300 ◦C. Shao et al [35] synthesized a MgH2/0.1TiH2 composite by ball milling Mg and Ti powders under initial hydrogen pressure of 30 MPa and found that its dehydrogenation temperature was 100 ◦C lower than that of pure MgH2. TiH1.971 with different particle sizes are prepared via a wet chemical ball milling method and the as-milled TiH1.971 nanoparticles are added to MgH2 to improve its hydrogen storage performance.

Experimental

Results and discussion

R2 R3 A2 A3

Conclusions