Abstract
Annulative η3‐allylpalladium chemistry has been a longstanding trending research topic since the 80's. Nowadays, this research area is still providing challenges to the catalysis community leading to the development original and brand‐new transformations. Several reaction partners have been used as precursors for η3‐allylpalladium species, namely allyl diacetates, allyl monoacetates, 3‐acetoxy‐2‐trimethylsilylmethyl‐1‐propene (ASMP), alkylidene cyclopropanes (ACPs), vinyl cyclopropanes (VCPs), vinyl aziridines, and vinyl epoxides. This minireview is intended to show the recent developments in the field of annulative η3‐allylpalladium chemistry with emphasis on new reactivity, enantioselective transformations as well as potential applications in total synthesis.
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