Abstract

The destruction of methyl tertiary butyl ether (MTBE) was studied using a Pt/Rh monolithic automotive catalyst. Inlet temperatures to the catalyst ranged from about 450 to about 775 K, and the amount of oxygen in the feed ranged from 0 to about 120% of stoichiometric. The presence of carbon dioxide, water and i-octane (2,2,4-trimethyl pentane) in the feed was also investigated. The decomposition of MTBE into methanol and i-butene (2-methyl-1-propene) was kinetically significant at these conditions. Both methanol and i-butene were present in the effluent from the catalyst at all operating conditions. Carbon dioxide and water had no significant effect on the kinetics of MTBE disappearance. The rate of MTBE destruction was faster than the oxidation of i-octane.

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