Abstract

In an effort to produce non-toxic and economically viable “green” protocols for waste water treatment, researchers are actively involved to develop versatile and effective silver nanoparticles (SNPs) as nano-catalyst from bio-based techniques. Since, p-nitrophenol (PNP) is one of the anthropogenic contaminants, considerable attention has been focused in catalytic degradability of PNP in wastewater treatment by curtailing serious effect on aquatic fauna. Ingestion of contaminants by aquatic organisms will not only affect the aquatic species but is also a potential threat to human health, especially if the toxic contaminants are involved in food chain. In this short report, we provided a comprehensive insight on few remarkable nanocatalysts especially based on SNPs and its biopolymer composites synthesized via ecofriendly “green” route. The beneficiality and catalytic performance of these silver nanocatalysts are concisely documented on standard model degradation reduction of PNP to p-aminophenol (PAP) in the presence of aqueous sodium borohydride. The catalytic degradation of PNP to PAP using SNPs follows pseudo first order kinetics involving six-electrons with lower activation energy. Furthermore, we provided a list of highly effective, recoverable, and economically viable SNPs, which demonstrated its potential as nanocatalysts by focusing its technical impact in the area of water remediation.

Highlights

  • Organic pollutants from industries are the major source for water pollution; these synthetic toxins are extremely harmful to the environment and influences health risks to human [1,2]

  • It is always beneficial if the silver nanoparticles (SNPs) were synthesized via non-hazardous ecofriendly routes rather than using toxic chemicals

  • Biodegradable polymers are an exceptional ideal choice for this kind of application [32,33,34], where metal nanocatalysts based on SNPs produced from plant-mediated ecofriendly routes with/without biopolymers as template materials can effectively serve the purpose

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Summary

Introduction

Organic pollutants from industries are the major source for water pollution; these synthetic toxins are extremely harmful to the environment and influences health risks to human [1,2]. Since the environmental impact of SNPs on various aquatic organisms are still principally unfamiliar, and the toxic effects of SNPs to organisms is mainly depend on the physicochemical characteristics of nanoparticles [11,12,13] It is always beneficial if the SNPs were synthesized via non-hazardous ecofriendly routes rather than using toxic chemicals. The important factor to consider in pollution remediation process is that employed material should not be another pollutant In this concern, biodegradable polymers are an exceptional ideal choice for this kind of application [32,33,34], where metal nanocatalysts based on SNPs produced from plant-mediated ecofriendly routes with/without biopolymers as template materials can effectively serve the purpose. The main objective of this short colloquy is to provide a general overview on the phyto-synthesis of some remarkable functional SNP catalysts and its biopolymer nanocomposites used especially in environmental remediation, for the catalytic degradation of industrial pollutant PNP

Phyto-Synthesis of Silver Nanoparticles and Its Biopolymer Nanocomposites
Catalytic Degradation of p-Nitrophenol Using Silver Nanoparticles
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