Catalytic decomposition of N2O over MxCo1−xCo2O4 (M = Ni, Mg) spinel oxides

Abstract

The catalytic decomposition of N2O to N2 and O2 was carried out on the MxCo1−xCo2O4 (M=Ni2+ and Mg2+, x=0.0–0.99) spinel catalysts. The results showed that the partial replacement of Co2+ by Ni2+ or Mg2+ in Co3O4 spinel oxide led to a significant improvement in the catalytic activity for the N2O decomposition, and the catalytic activity depended on the degree of Co2+ substitution by Ni2+ or Mg2+. The conversion of N2O reached 100% over the Ni0.74Co0.26Co2O4 and Mg0.54Co0.46Co2O4 catalysts at 200°C and 300°C in the absence and presence of excess O2 and water steam, respectively.