Abstract
Dinuclear copper and cyclic trinuclear cobalt complexes with pyrazolate and OH − bridges are able to decompose dimethyldioxirane in acetone, triggering radical reactions. Some products of reactions between organic substrates (cyclohexene or ethylbenzene) or acetone with secondary radicals formed from dimethyldioxirane: hydroxyl, methyl and acetomethyl, were identified and quantified. Tested complexes were also able to homolytically decompose cyclic acetone triperoxide and the radicals formed induced homolytic oxidation of cyclohexene producing 2-cyclohexen-1-ol and 2-cyclohexen-1-one at moderate yield.
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