Catalytic Decomposition of an Ionic Liquid Monopropellant Over Ir/Hexaaluminate Catalysts.

Abstract

The aim of this study is to elucidate the influence of an iridium loading strategy over hexaaluminate on the catalytic performance during the decomposition of liquid monopropellants based on ammonium dinitramide (ADN). Powder-type and pellet-type Ir/hexaaluminate catalysts were prepared and their chemico-physical properties were characterized by N₂ adsorption, XRD, XRF, and SEM. There were considerable differences in the Ir amounts present on the surface according to the impregnation method employed. The catalytic activities of three types of Ir/hexaaluminate catalysts to decompose the ADN-based liquid monopropellant were compared using a semi-batch type of reactor. Pellet-type Ir/hexaaluminate catalyst, which formed hexaaluminate into a pellet and where iridium was impregnated during the last stage, showed the lowest onset temperature during the decomposition of the ADN-based liquid monopropellant, having the effect of lowering the decomposition onset temperature by around 60 °C compared to that without a catalyst. This was due to the pellet-type Ir/hexaaluminate having a larger surface area and a large number of Ir active sites on its surface.