Catalytic Combustion of Ethyl Acetate over Nanostructure Cobalt Supported ZSM‐5 Zeolite Catalysts

Abstract

Abstract Gas phase catalytic combustion of ethyl acetate, as one of volatile organic compounds (VOC), was studied on nanostructure ZSM‐5, HZSM‐5 and Co‐ZSM‐5 with different cobalt loadings. Nanostructure of ZSM‐5 was determined by XRD, SEM and TEM. Catalytic studies were carried out under atmospheric pressure in a fixed bed reactor. Results showed that the Co‐ZSM‐5 catalysts had better activity than others and at temperatures below 350 °C, amount of Co loading was more effective on catalytic activity. The order of conversion of ethyl acetate over different Co loading is as follows: Co‐ZSM‐5 (0.75 wt%)<Co‐ZSM‐5 (1.5 wt%)<Co‐ZSM‐5 (15 wt%)<Co‐ZSM‐5 (2.8 wt%). Besides the higher the inlet concentration of ethyl acetate, the lower the conversion yield, and oxygen concentration in catalytic oxidation conditions has not so large influence on conversion. Furthermore, the presence of water vapor in inlet gaseous feed has an inhibitive effect on ethyl acetate conversion and at the temperatures above 400?C, the effect decreases.