Abstract
The development of effective methods for promoting the carbon-nitrogen bond formation has long been a challenge in catalysis. However the addition of amines to olefins to yield alkylamines, is surprisingly catalyzed more efficiently by alkali metal amides, rather than by transition metal complexes [1]. On the other hand different routes to the metal promoted C-N bond formation lead to a different type of products. These catalytic syntheses involve the interaction of carbon monoxide with organic azides, RN3 [2–4], with aromatic nitro compounds, ArNO2 [5], and with amines in the presence of molecular oxygen [6–8] (Scheme 1).KeywordsNitro CompoundNitrene ComplexOxidative CarbonylationAromatic Nitro CompoundOrganic AzideThese keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
