Abstract
Three-dimensional porous carbon was prepared via a hard templating method using a colloidal crystal of monodispersed silica nanospheres (SNSs). Platinum nanoparticle catalyst on thus prepared porous carbon was prepared by a liquid-phase method using hydrogen hexachloroplatinate (IV) hexahydrate as Pt source in the presence of ethylene glycol. The prepared Pt catalyst on the carbon was characterized in detail and applied for the C-methylation reaction to elucidate the influence of the pore structure and morphology of the replicated porous carbon supports.
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