Abstract
A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol has been designed and developed. These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation, Rh-catalyzed asymmetric hydrogenation and hydroformylation, and Cu-catalyzed conjugate addition reactions.
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