Abstract
AbstractAsymmetric dihydroxylation of alkenes is one of the cornerstone reactions in organic synthesis, providing a direct entry to optically active vicinal diols, which are not only a subunit in natural products but also versatile building blocks. In recent years, considerable progress in catalytic asymmetric osmium-free dihydroxylation has been achieved. This short review presents a concise summary of the reported methods of catalytic asymmetric osmium-free dihydroxylation.1 Introduction2 Iron-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes3 Manganese-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes4 Palladium/Gold Bimetallic Nanocluster-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes5 Enzyme-Catalyzed Asymmetric anti-Dihydroxylation of Alkenes6 Amine-Catalyzed Asymmetric Formal anti-Dihydroxylation of Enals7 Diselenide-Catalyzed anti-Dihydroxylation of Alkenes8 Molybdenum-Catalyzed Asymmetric anti-Dihydroxylation of Allylic Alcohols9 Phase-Transfer-Catalyzed Asymmetric Dihydroxylation of α-Aryl Acrylates10 Conclusion
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