Abstract
Manganese complex of the optically active salen ligand [ N,N'-bis[( S)-3-(1-phenylpropyl)salicylidene]-(1 R,2 R)-1,2-diphenylethylenediaminato] was found to be an effective catalyst for the enantioselective epoxidation of unfunctionalized olefins. The highest enantioselectivity of 50% ee was realized for ( E)-1-phenyl-1-propene.
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