Catalytic Asymmetric Cycloaddition of Ketenes and Nitroso Compounds: Enantioselective Synthesis of α‐Hydroxycarboxylic Acid Derivatives

Maximilian Dochnahl,Gregory C Fu

doi:10.1002/ange.200805805

Catalytic Asymmetric Cycloaddition of Ketenes and Nitroso Compounds: Enantioselective Synthesis of α‐Hydroxycarboxylic Acid Derivatives

Maximilian Dochnahl, Gregory C Fu

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https://doi.org/10.1002/ange.200805805

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Journal: Angewandte Chemie	Publication Date: Mar 10, 2009
Citations: 20

Affiliation: Massachusetts Institute of Technology

#Nitroso Compounds #Acid Derivatives + Show 5 more

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Abstract

AbstractEine gute Wahl des chiralen Katalysators und der Ausgangsverbindungen ermöglicht den Aufbau von 1,2‐Oxazetidin‐3‐onen durch hoch regio‐ und enantioselektive Cycloadditionen von Ketenen mit Nitrosoverbindungen. Die Produkte sind für sich schon potenziell bioaktive Substanzen und können überdies in weitere wichtige Verbindungsklassen überführt werden, z. B. in α‐Hydroxycarbonsäure‐Derivate.magnified image

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