Abstract

Activity of palladium catalysts on different crystalline and amorphous supports was studied using hydrogenation of 1-phenylethenylphosphonic acid with molecular hydrogen as an example. Nanoscale Pd0 deposited on the surface of multi-wall carbon nanotubes (MWCNT) supported on microparticles of titanium oxide has proved the highest efficiency. The starting acid was quantitatively reduced for 1 h in the presence of this catalyst, 11 cycles of hydrogenation were carried out without loss of catalytic activity.

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