Abstract
Dehydrogenative coupling reactions of various silanes with alcohols, reductive coupling reactions of silanes with carbonyl compounds as well as dehydration of silanols are studied for silicon oxygen bond formation reactions under catalytic conditions. The dehydrogenative coupling reactions are catalysed by amines and metal catalysts derived from copper(II), gold(III), silver(I) palladium(II), rhodium(I), platinum(II) complexes, whereas reductive coupling reactions between quinone and different silanes are done by rhodium(I) and palladium(II) catalysts. Under near neutral condition dehydration of silanols can be caused by amines such as triethylenetetramine.
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