Abstract
The review presents a comparative analysis of promising homogeneous metal complex catalysts and presents the results of studies on the synthesis and determination of the structural characteristics of effective catalysts for the oxidation of organic compounds with hydrogen peroxide – Q3{PO4[WO(O2)2]4} (Q is a quaternary ammonium cation) – using methods EXAFS, SAXS, NMR, Raman and IR spectroscopy. The possibilities of using bifunctional homogeneous peroxopolyoxo complexes of metals in combination with organic cations having quaternized nitrogen under the conditions of interfacial catalysis are considered, using examples of reactions of oxidation of various classes of organic compounds with hydrogen peroxide to obtain popular products – aliphatic and aromatic epoxides, mono- and dicarboxylic acids, as well as biologically active compounds for medical and agro-industrial purposes.
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