Catalyst-regulated conversion of p-phenylenediamine-based carbon dots from red to deep-blue emission

Abstract

Deep-blue emission (＜450 nm) is significant in high-density information storage, solid-state lighting, and vivid displays. However, the carbon dots (CDs) obtained from p-phenylenediamine (pPD) have only red fluorescence, which greatly limits the application and development of pPD-based CDs. As we all know, a catalyst is a substance that can change the rate and pathway of a chemical reaction. Herein, we designed to add a catalyst to realize the conversion of pPD-based CDs from red to deep-blue fluorescence. The emission peak of obtained deep-blue CDs was 440 nm, and the full-width at half-maximum (FWHM) was only 58 nm, with a high color purity. In addition, through in-depth analysis of microstructure and photoluminescence (PL) properties, it is found that the decrease of the sp2-conjugated domain and the graphite N content and the increase in pyridinic N content were the main reasons for the blue shift of the spectra. Based on this, the formation process and mechanism of red and deep-blue CDs were further elucidated. This work not only efficiently realized the design of the deep-blue CDs but also provided a new idea for the luminescence regulation of CDs without changing the raw materials and reaction conditions.